Highly Active and Robust Ruthenium Complexes Based on Hemilability of Hybrid Ligands for C-H Oxidation
Chun-Bo Bo, Qingqing Bu, Xue Li, Ge Ma, Donghui Wei*, Cheng Guo*, Bin Dai and Ning Liu*
*Zhengzhou University, Zhengzhou, Henan 450001; Zhejiang University School of Medicine, Hangzhou, Zhejiang 310009; Shihezi
University, Shihezi, Xinjiang 832003, PRC,
Email: donghuiwei
zzu.edu.cn, cheng_guozju.edu.cn,
ningliushzu.edu.cn
C.-B. Bo, Q. Bu, X. Li, G. Ma, D. Wei, C. Guo, B. Dai, N. Liu, J. Org. Chem., 2020, 85, 4324-4334.
DOI: 10.1021/acs.joc.0c00025
Abstract
Ru complexes with tridentate hybrid ligands showed a very strong catalytic activity in water at room temperature for benzylic C-H oxidation. Whereas NHCs with a stronger donor ability stabilize the Ru center; nitrogen ligands with a relatively weaker donor ability release from the Ru center, so that they induce a reaction.
see article for more examples
While ads financed 62% of the published abstracts in 2024, donations allowed us to publish additional 12%. 26% of the abstracts have been published voluntarly. If you kindly donate, we can publish more freely accessible information and help the chemical community even more:
If you don't like pawalls or a flood of more and more advertising, then you can send a clear signal here!
Key Words
ID: J42-Y2020
