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C-Aryl Glycosylation: Palladium-Catalyzed Aryl-Allyl Coupling of Achmatowicz Rearrangement Products with Arylboronic Acids

Ming Wai Liaw, Wai Fung Cheng and Rongbiao Tong*

*Department of Chemistry, The Hong Kong University of Science and Technology, Clearwater Bay, Kowloon, Hong Kong, China, Email: rtongust.hk

M. W. Liaw, W. F. Cheng, R. Tong, J. Org. Chem., 2020, 85, 6663-6674.

DOI: 10.1021/acs.joc.0c00688


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Abstract

A Pd-catalyzed arylation of Achmatowicz rearrangement products with arylboronic acids provides synthetically versatile C-aryl dihydropyranones under mild conditions.

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Key Words

2H-pyran-5-ones


ID: J42-Y2020