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Chemoselective Rhodium-Catalyzed Borylation of Bromoiodoarenes Under Mild Conditions

Anthony J. Varni, Michael V. Bautista and Kevin J.T. Noonan*

*Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213-2567, United States, Email:

A. J. Varni, M. V. Bautista, K. J. T. Noonan, J. Org. Chem., 2020, 85, 6770-6777.

DOI: 10.1021/acs.joc.0c00178

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A rhodium-catalyzed borylation with excellent selectivity for C-I bonds provides aryl boronate esters under mild conditions. The reaction exhibits broad functional group tolerance.

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Key Words


ID: J42-Y2020