Organic Chemistry Portal

Abstracts

Search:

Chemoselective Rhodium-Catalyzed Borylation of Bromoiodoarenes Under Mild Conditions

Anthony J. Varni, Michael V. Bautista and Kevin J.T. Noonan*

*Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213-2567, United States, Email: noonanandrew.cmu.edu

A. J. Varni, M. V. Bautista, K. J. T. Noonan, J. Org. Chem., 2020, 85, 6770-6777.

DOI: 10.1021/acs.joc.0c00178 (free Supporting Information)


see article for more reactions

Abstract

A rhodium-catalyzed borylation with excellent selectivity for C-I bonds provides aryl boronate esters under mild conditions. The reaction exhibits broad functional group tolerance.


see article for more examples



Key Words

arylboronates


ID: J42-Y2020