Convenient and Efficient Suzuki-Miyaura Cross-Coupling Catalyzed by a Palladium/Diazabutadiene System

Gabriela A. Grasa, Anna C. Hillier and Steven P. Nolan

*Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148, Email: steven.nolanugent.be

G. A. Grasa, A. C. Hillier, S. P. Nolan, Org. Lett., 2001, 3, 1077-1080.

DOI: 10.1021/ol015676t

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Abstract

A combination of a diazabutadiene and Pd(OAc)₂ catalyzes the Suzuki-Miyaura cross-coupling of various aryl bromides and activated aryl chlorides with arylboronic acids.

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Key Words

Suzuki coupling, biaryl synthesis

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ID: J54-Y2001