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Diselenide-Mediated Catalytic Functionalization of Hydrophosphoryl Compounds

Handoko, Zacharia Benslimane and Paramjit S. Arora*

*Department of Chemistry, New York University, 100 Washington Square East, New York, New York 10003, United States, Email:

Handoko, Z. Benslimane, P. S. Arora, Org. Lett., 2020, 22, 5806-5810.

DOI: 10.1021/acs.orglett.0c01858

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A diaryldiselenide catalyzes a cross-dehydrogenative nucleophilic functionalization of hydrophosphoryl compounds. Phosphorus and selenium NMR studies reveal the existence of a P-Se bond intermediate, and structural analyses indicate a stereospecific reaction.

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proposed mechanism

Key Words

P-N Bond Formation, oxygen

ID: J54-Y2020