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A One-Step Approach to N-(Hetero)aryl-3,5-dinitropyrazoles from (Hetero)aryl Amines

Haifeng Huang, Yameng Shi, Hui Li, Hongli Li, Aimin Pang* and Jun Yang*

*Hubei Institute of Aerospace Chemotechnology, Xiangyang, Hubei 441003; SIOC, Chinese Academy of Sciences, Shanghai 200032, PR China, Email: ppamtom.com, yangjsioc.ac.cn

H. Huang, Y. Shi, H. Li, H. Li, A. Pang, J. Yang, Org. Lett., 2020, 22, 5866-5869.

DOI: 10.1021/acs.orglett.0c01960


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Abstract

Potassium 1,1,3,3-tetranitropropane-1,3-diide reacts readily with various (hetero)aryl amines to give the corresponding N-(hetero)aryl-3,5-dinitropyrazoles in good yields.

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Key Words

pyrazoles


ID: J54-Y2020