Nickel-Catalyzed Thiocarbonylation of Arylboronic Acids with Sulfonyl Chlorides for the Synthesis of Thioesters
Xinxin Qi, Zhi-Peng Bao, Xin-Tong Yao and Xiao-Feng Wu*
*Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, Rostock 18059, Germany,
Email: xiao-feng.wu
catalysis.de
X. Qi, Z.-P. Bao, X.-T. Yao, X.-F. Wu, Org. Lett., 2020, 22, 6671-6676.
DOI: 10.1021/acs.orglett.0c02541
Abstract
A nickel-catalyzed thiocarbonylation of arylboronic acid with sulfonyl chlorides in the presence of Mo(CO)6 as CO source and reductant provides a broad range of thioesters in good yields with good functional group tolerance.
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Key Words
Carboxylations, Thioesters, Multicomponent Reactions
ID: J54-Y2020
