Electrochemical Alkoxyhalogenation of Alkenes with Organohalides as the Halide Sources via Dehalogenation

Ting-Ting Zhang, Mu-Jia Luo*, Yang Li, Ren-Jie Song and Jin-Heng Li*

*State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, China, Email: luomjchem163.com, jhlihnu.edu.cn

T.-T. Zhang, M.-J. Luo, Y. Li, R.-J. Song, J.-H. Li, Org. Lett., 2020, 22, 7230-7233.

DOI: 10.1021/acs.orglett.0c02582

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Abstract

Electrochemical technology enables alkene alkoxyhalogenation and organohalide dehalogenation in one pot. Anodic conversion of the C=C bond to radical cation intermediates and cathodic transformations of organohalides run in parallel.

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Key Words

bromohydrins, ethers, multicomponent reactions, electrochemistry

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ID: J54-Y2020