Allylic Amination of Alkenes with Iminothianthrenes to Afford Alkyl Allylamines
Qiang Cheng, Junting Chen, Songyun Lin and Tobias Ritter*
*Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr, Germany
Email: ritter
mpi-muelheim.mpg.de
Q. Cheng, J. Chen, S. Lin, T. Ritter, J. Am. Chem. Soc., 2020, 142, 17287-17293.
DOI: 10.1021/jacs.0c08248
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Abstract
The reactivity of thianthrene-based nitrogen sources enables allylic amination of alkenes to directly afford alkyl allylamines. Iminothianthrenes can be prepared from primary amines in a single step.
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Key Words
allylic amines, photochemistry
ID: J48-Y2020
