Photo-Mediated Decarboxylative Giese-Type Reaction Using Organic Pyrimidopteridine Photoredox Catalysts
Firas El-Hage, Christopher Schöll and Jola Pospech*
*Leibniz Institute for Catalysis, Albert-Einstein-Straße 29a, 18059 Rostock, Germany,
Email: Jola.Pospech
catalysis.de
F. El-Hage, C. Schöll, J. Pospech, J. Org. Chem., 2020, 85, 13853-13867.
DOI: 10.1021/acs.joc.0c01955
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Abstract
Pyrimidopteridine N-oxides as organic photoredox-active catalysts mediate a metal-free photoinduced decarboxylative Giese-type addition of carboxylic acids to a variety of electron-deficient alkenes.
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Key Words
1,4-additions, cyclopentanones, organocatalysis, photochemistry
ID: J42-Y2020
