Electron Donor-Acceptor Complex-Initiated Photochemical Cyanation for the Preparation of α-Amino Nitriles
Qing Xia, Yufei Li, Lan Cheng, Xin Liang, Chenlin Cao, Peng Dai, Hongping Deng, Weihua Zhang* and Qingmin Wang*
*Nanjing Agricultural University, Nanjing 210095; Nankai
University, Tianjin 300071, China, Email: zhangwh
njau.edu.cn,
wangqmnankai.edu.cn
Q. Xia, Y. Li, L. Cheng, X. Liang, C. Cao, P. Dai, H. Deng, W. Zhang, Q. Wang, Org. Lett., 2020, 22, 9638-9643.
DOI: 10.1021/acs.orglett.0c03703
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Abstract
An electron donor-acceptor complex-initiated α-cyanation of tertiary amines proceeds smoothly without the presence of photocatalysts and transition metal catalysts to provide various α-amino nitriles under mild conditions.
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Key Words
tetrahydroisoquinolines, photochemistry
ID: J54-Y2020
