New Ammonia Equivalents for the Pd-Catalyzed Amination of Aryl Halides
Xiaohua Huang and Stephen L. Buchwald*
*Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, Email: sbuchwalmit.edu
X. Huang, S. L. Buchwald, Org. Lett., 2001, 3, 3417-3419.
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LiN(SiMe3)2, Ph3SiNH2, and LiNH2 can be be used as ammonia equivalents for the Pd-catalyzed coupling of aryl halides to provide simple anilines, including ortho-substituted ones, as well as di- and triarylamines.
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Buchwald-Hartwig Coupling, Anilines