Visible-Light Decatungstate/Disulfide Dual Catalysis for the Hydro-Functionalization of Styrenes
Alexis Prieto* and Marc Taillefer*
*ICGM, Univ Montpellier, CNRS, ENSCM, 34000 Montpellier, France,
Email: alexis.prieto
enscm.fr, marc.tailleferenscm.fr
A. Prieto, M. Taillefer, Org. Lett., 2021, 23, 1484-1488.
DOI: 10.1021/acs.orglett.1c00189
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Abstract
The combination of a decatungstate and a disulfide catalyzes hydrocarbamoylation, -acylation, -alkylation, and -silylation of styrenes under visible light irradiation. In this photoredox methodology, the use of a disulfide as a cocatalyst is crucial for the reaction efficiency. This photoredox system provides a broad range of useful building blocks and high-value molecules.
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Key Words
hydrocarbamoylation, photochemistry
ID: J54-Y2021
