Visible-Light-Driven Phosphonoalkylation of Alkenes
Yue-Ming Jiang, Jie Liu, Qiang Fu*, Yu-Ming Yu*, Da-Gang Yu*
*Sichuan University, #29 Wangjiang Road, Chengdu 610064; Xinjiang University, Urumqi 830046, Xinjiang, P. R. of China
Email: yym2009
iccas.ac.cn, dgyuscu.edu.cn,
fuqiangswmu.edu.cn
Y.-M. Jiang, J. Liu, Q. Fu, Y.-M. Yu, D.-G. Yu, Synlett, 2021, 32, 378-382.
DOI: 10.1055/s-0040-1706681
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Abstract
A visible-light-driven redox-neutral phosphonoalkylation of alkene-bearing alkyl sulfonates provides a variety of organophosphorus-containing three-membered carbocyclic scaffolds. The transition-metal-free protocol displays good functional group tolerance, broad substrate scope, high yields, and mild reaction conditions.
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4CzIPN
Key Words
photochemistry, redox-neutral, difunctionalization of alkenes, cyclopropanes, phosphine oxides, phosphonates
ID: J72-Y2021
