Diastereodivergent Intermolecular 1,2-Diamination of Unactivated Alkenes Enabled by Iodine Catalysis
Satoshi Minakata*, Hayato Miwa, Kenya Yamamoto, Arata Hirayama and Sota Okumura
*Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan,
Email: minakata
chem.eng.osaka-u.ac.jp
S. Minakata, H. Miwa, K. Yamamoto, A. Hirayama, S. Okumura, J. Am. Chem. Soc., 2021, 143, 4112-4118.
DOI: 10.1021/jacs.1c00228
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Abstract
Iodine catalyzes stereospecific 1,2-diaminations of unactivated alkenes. Depending on the nitrogen source and the configuration of the alkenes, two methods provide access to all disastereomeric forms of 1,2-diamines.
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Key Words
1,2-diamines, sodium hypochlorite
ID: J48-Y2021
