Nickel-Catalyzed Hydrodeoxygenation of Aryl Sulfamates with Alcohols as Mild Reducing Agents
Kasumi Matsuo, Masami Kuriyama*, Kosuke Yamamoto, Yosuke Demizu, Koyo Nishida, Osamu Onomura*
*Graduate School of Biomedical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan, Email: mkuriyamnagasaki-u.ac.jp, onomuranagasaki-u.ac.jp
K. Matsuo, M. Kuriyama, K. Yamamoto, Y. Demizu, K. Nishida, O. Onomura, Synthesis, 2021, 53, 4449-4460.
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A nickel-catalyzed hydrodeoxygenation of aryl sulfamates enables the use of alcohols as mild reductants. A variety of functional groups and heterocycles were tolerated in this reaction system to give the desired products in high yields.
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