Palladium-Catalyzed Decarbonylative Borylation of Aryl Anhydrides
Wenzhi Zhang, Fusheng Bie, Jie Ma, Fengyan Zhou, Michal Szostak* and Chengwei Liu*
*Rutgers University, 73 Warren Street, Newark, New Jersey 07102, USA; NIUST, 219 Ningliu Road, Nanjing, Jiangsu 210044, China, Email: michal.szostakrutgers.edu, chengwei.liunuist.edu.cn
W. Zhang, F. Bie, J. Ma, F. Zhou, M. Szostak, C. Liu, J. Org. Chem., 2021, 86, 17445-17452.
DOI: 10.1021/acs.joc.1c02134
Abstract
The combination of Pd(OAc)2/dppb catalyzes a base-free decarbonylative borylation of readily available and bench stable aryl anhydrides as aryl electrophiles. This method offers an excellent functional group tolerance and broad substrate scope.
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proposed mechanism
Key Words
ID: J42-Y2021