Organic Chemistry Portal

Abstracts

Search:

Palladium-Catalyzed Decarbonylative Borylation of Aryl Anhydrides

Wenzhi Zhang, Fusheng Bie, Jie Ma, Fengyan Zhou, Michal Szostak* and Chengwei Liu*

*Rutgers University, 73 Warren Street, Newark, New Jersey 07102, USA; NIUST, 219 Ningliu Road, Nanjing, Jiangsu 210044, China, Email: michal.szostakrutgers.edu, chengwei.liunuist.edu.cn

W. Zhang, F. Bie, J. Ma, F. Zhou, M. Szostak, C. Liu, J. Org. Chem., 2021, 86, 17445-17452.

DOI: 10.1021/acs.joc.1c02134



Abstract

The combination of Pd(OAc)2/dppb catalyzes a base-free decarbonylative borylation of readily available and bench stable aryl anhydrides as aryl electrophiles. This method offers an excellent functional group tolerance and broad substrate scope.

see article for more examples

proposed mechanism



Key Words

arylboronates


ID: J42-Y2021