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Visible-Light-Induced N-Acylation of Sulfoximines

Pan Qiu, Xuelun Duan, Ming Li, Yubin Zheng and Wangze Song*

*State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P.R. China, Email: wzsongdlut.edu.cn

P. Qui, X. Duan, M. Li, Y. Zheng, W. Song, Org. Lett., 2022, 24, 2733-2737.

DOI: 10.1021/acs.orglett.2c00843


Abstract

The use of an organic photoredox catalyst enables a metal-, base-, and additive-free N-acylation of sulfoximines under mild conditions. This green strategy offers broad substrate scope, good compatibility with air, and high yields.

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proposed mechanism



Key Words

sulfoximines, photochemistry


ID: J54-Y2022