Microwave-Assisted Hydrogen-Free Reductive Deiodination of Iodoarenes with Silicon-Nanoarray Palladium-Nanoparticle Catalyst
Yuta Matsukawa, Yoichi M. A. Yamada*
*RIKEN Center for Sustainable Resource Science, Wako,
Saitama, 351-0198, Japan,
Email: ymayamada
riken.jp
Y. Matsukawa, Y. M. A. Yamada, Synlett, 2022, 33, 777-780.
DOI: 10.1055/a-1795-8092
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Abstract
A silicon nanoarray palladium catalyst mediates a hydrogenolysis of iodoarenes under microwave irradiation in the presence of triethanolamine as the sacrificial reductant. The reductive deiodination proceeded under an aerobic atmosphere affording the corresponding hydrogen-substituted arenes in high yields. No reaction occurred in the absence of microwaves.
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Key Words
microwave synthesis, dehalogenation, deiodination, reductive dehalogenation, iodoarenes, triethanolamine, palladium, silicon nanowire array
ID: J72-Y2022
