Organic Chemistry Portal

Abstracts

Search:

Well-Defined Phosphine-Free Manganese(II)-Complex-Catalyzed Synthesis of Quinolines, Pyrroles, and Pyridines

Ankur Maji, Shivangi Gupta, Milan Maji and Sabuj Kundu*

*Department of Chemistry, Indian Institute of Technology, Kanpur, Uttar Pradesh 208016, India, Email: sabujiitk.ac.in

A. Maji, S. Gupta, M. Maji, S. Kundu, J. Org. Chem., 2022, 87, 8351-8367.

DOI: 10.1021/acs.joc.2c00167


see article for more reactions

Abstract

A simple, phosphine-free, and inexpensive catalytic system based on a manganese(II) complex mediates the synthesis of different important N-heterocycles such as quinolines, pyrroles, and pyridines from amino alcohols and ketones.

see article for more examples

proposed mechanism



Key Words

quinolines


ID: J42-Y2022