Synthesis of Cyclic Phosphinates by Microwave-Assisted Ionic-Liquid-Promoted Alcoholysis
Nikoletta Harsági, Nóra Zsuzsa Kiss, László Drahos, György Keglevich*
*Department of Organic Chemistry and Technology, Budapest, University of Technology and Economics, 1521 Budapest, Hungary, Email: keglevich.gyorgyvbk.bme.hu
N. Harsági, N. Z. Kiss, L. Drahos, G. Keglevich, Synthesis, 2022, 54, 3899-3905.
DOI: 10.1055/a-1504-8924
see article for more reactions
Abstract
A series of 1-alkoxy-3-methyl- and 3,4-dimethyl-3-phospholene 1-oxides, as well as 1-alkoxy-3-methylphospholane 1-oxides were prepared in good yields by a microwave-assisted and [bmim][PF6]-catalyzed transesterification of the corresponding methyl or ethyl esters.
see article for more examples
Key Words
alcoholysis, transesterification, phospholene oxide, phospholane oxide, microwave synthesis, ionic liquids
ID: J66-Y2022