Heterogeneous Photocatalytic Radical Synthesis of Aryl Allyl Sulfones
Liang Wang*, Ling-feng Zhang
*School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou 213164, P. R. of China,
Email: lwcczu
126.com
L. Wang, L.-f. Zhang, Synlett, 2022, 33, 1929-1932.
DOI: 10.1055/s-0042-1752344
Abstract
A polyaniline-graphitic carbon nitride-titanium dioxide composite catalyzes a radical cascade reaction of an aryl diazonium salt, DABCO·(SO2)2 and 3-bromoprop-1-ene to provide aryl allyl sulfones under visible light irradiation. A series of substrates were tolerated, providing the corresponding products in good yields. Moreover, the photocatalyst could be readily recovered and reused several times.
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Key Words
photochemistry, heterogeneous catalysis, semiconductor catalyst, radical cascade reaction, multicomponent reactions, aryl sulfones, allyl sulfones
ID: J72-Y2022
