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Selectfluor-Mediated Oxidative Dehydrogenation of Hydrazines: A Process for the Synthesis of Azo Compounds

Yulei Zhao*, Shuai Li, Jinjie Cui, Huimin Wang, Xin Kang, Yan Wang, Laijin Tian

*School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, P. R. of China, Email:

Y. Zhao, S. Li, J. Cui, H. Wang, X. King, Y. Wang, L. Tian, Synthesis, 2022, 54, 5245-5252.

DOI: 10.1055/a-1899-5563

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Selectfluor mediates an oxidative dehydrogenation of hydrazine derivatives via N-fluorination and elimination processes to provide azo compounds. This reaction offers simple operation, mild conditions, good functional group tolerance, and high efficiency.

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Key Words

oxidation, dehydrogenation, azo compounds, hydrazines, Selectfluor

ID: J66-Y2022