Mesoporous Graphitic Carbon Nitride Photocatalyzed Switchable Divergent Perfluoroalkylation of Terminal Alkynes
Xiaolin Shi, Tao Song, Qinglin Li, Xiuling Guo and Yong Yang*
*Qingdao Institute of Bioenergy and Bioprocess Technology,
Chinese Academy of Sciences (CAS), Qingdao, Shandong 266101, People’s Republic
of China, Email: yangyong
qibebt.ac.cn
X. Shi, T. Song, Q. Li, X. Guo, Y. Yang, Org. Lett., 2022, 24, 8724-8728.
DOI: 10.1021/acs.orglett.2c03814
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Abstract
The use of mesoporous graphitic carbon nitride (mpg-CN) as a recyclable, nontoxic, and heavy-metal-free photocatalyst enables an efficient, eco-friendly, and divergent perfluoroalkylation of terminal alkynes. Switching the reaction solvents provides libraries of perfluoroalkylated alkynes, alkenes, and alkenyl iodides to be synthesized in good yields.
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Key Words
perfluoroalkylation, alkynes, photochemistry
ID: J54-Y2022
