Sn(OTf)2-Catalyzed Allylic Substitution of Thiols to Allyl Alcohols: Access to Allyl Sulfides
Yibo Chen, Zhenbo Gao*
*Jiangsu Key Laboratory of Pesticide Science, Department of Chemistry, College of Sciences, Nanjing Agricultural University, Nanjing
210095, China, Email: zgao
njau.edu.cn
Y. Chen, Z. Gao, Synthesis, 2022, 54, 5291-5299.
DOI: 10.1055/s-0041-1738424
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Abstract
Sn(OTf)2 catalyzes a mild and efficient synthesis of allyl sulfides from allyl alcohols and thiols as substrates in dichloromethane at room temperature. A diverse range of allyl sulfides have been obtained with good to excellent yields after a reaction time of 12 hours.
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Key Words
allyl alcohols, allyl sulfides, allylic substitution, C-S bond formation, thiols
ID: J66-Y2022
