Redox-Neutral Strategy for Sulfilimines Synthesis via S-Arylation of Sulfenamides
Guoling Huang, Xunbo Lu* and Fangpeng Liang
*Laboratory of Marine Green Fine Chemicals, School of Chemistry and Chemical Engineering, Lingnan
Normal University, 29 Cunjin Road, Zhanjiang 524048, P. R. China,
Email: luxunbo
foxmail.com
G. Huang, X. Lu, F. Liang, Org. Lett., 2023, 25, 3179-3183.
DOI: 10.1021/acs.orglett.3c01077
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Abstract
A transition-metal-free and redox-neutral S-arylation of sulfenamides with diaryliodonium salts provides sulfilimines in very good yields and with superlative chemoselectivity under exceptionally mild conditions.
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Redox-Neutral Synthesis of Sulfilimines through the S-Alkylation of Sulfenamides
G. Huang, X. Lu, K. Yang, X. Xu, Org. Lett., 2023, 25, 3173-3178.
Key Words
ID: J54-Y2023
