Nickel-Catalyzed Isomerization of Homoallylic Alcohols
Dustin D. Youmans, Hai N. Tran and Levi M. Stanley*
*Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States,
Email: lstanley
iastate.edu
D. D. Youmans, H. N. Tran. L. M. Stanley, Org. Lett., 2023, 25, 3559-3563.
DOI: 10.1021/acs.orglett.3c01201
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Abstract
Nickel-catalyzed isomerizations of homoallylic alcohols provide ketone products are generated in very good yield. These isomerization reactions occur in the presence of a simple nickel catalyst that does not require addition of an exogenous ligand.
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proposed mechanism
Key Words
ID: J54-Y2023
