Photocatalytic Charge-Transfer Complex Enables Hydroarylation of Alkenes for Heterocycle Synthesis
Ying-Zheng Ren, Chang-Zhen Fang, Bei-Bei Zhang, Lin He*, Yong-Liang Tu* and Xiang-Yu Chen*
*Shihezi University, Shihezi, Xinjiang 832000; University of Chinese Academy of Sciences Beijing 100049,
China,
Email: helinshzu.edu.cn, tuyongliang
ucas.ac.cn,
chenxiangyu20
ucas.ac.cn
Y.-Z. Ren, C.-Z. Fang, B.-B. Zhang, L. He, Y.-L. Tu, X.-Y. Chen, Org. Lett., 2023, 25, 3585-3589.
DOI: 10.1021/acs.orglett.3c01329
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Abstract
A photocatalytic CTC strategy for hydroarylation of both activated and unactivated alkenes via single-electron reduction using thiolate as a catalytic electron donor enables the synthesis of various polycyclic heterocycle molecules from N-arylacrylamides, N-methacryloyl benzamides, and alkenyl-substituted quinazolinones.
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proposed mechanism
Key Words
Oxindoles, Photochemistry
ID: J54-Y2023