Rhodium-Catalyzed Regio- and Enantioselective Allylic Sulfonylation from Sulfonyl Hydrazides
Sajid Ur Rehman and Changkun Li*
*School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China,
Email: chkli
sjtu.edu.cn
S. U. Rehman, C. Li, Org. Lett., 2023, 25, 3693-3697.
DOI: 10.1021/acs.orglett.3c01124
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Abstract
A highly regio- and enantioselective allylic sulfonylation of racemic branched allylic carbonates and Z and E linear allylic carbonates with readily available sulfonyl hydrazides provides branched allylic sulfones in very good yields with high regio- and enantioselectivities.
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proposed mechanism
Key Words
ID: J54-Y2023
