Effect of Solvent on the Rate of Ozonolysis: Development of a Homogeneous Flow Ozonolysis Protocol
Danniel K. Arriaga, Seokmin Kang and Andy A. Thomas*
*Department of Chemistry, Texas A&M University, College Station, Texas 77842-0001, United States,
Email: andythomas
tamu.edu
D. K. Arriaga, S. Kang, A. A. Thomas, J. Org. Chem., 2023, 88, 13720-13726.
DOI: 10.1021/acs.joc.3c01372
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Abstract
The effect of organic solvents on ozone solubility and the rate of ozonolysis reactions were determined using rapid injection NMR spectroscopy. The tabulated solubility and kinetic data allowed for the design of a homogeneous ozonolysis flow reactor capable of delivering precise quantities of dissolved ozone to various olefin substrates.
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reaction set-up
Key Words
ozonolysis, ozone, flow chemistry
ID: J42-Y2023
