Palladium/Charcoal-Catalysed Olefin Reduction for the Simple and Efficient Synthesis of Substituted gem-Diborylalkanes
Kanak Kanti Das, Debraj Ghorai, Somenath Mahato, Santanu Panda*
*Indian Institute of Technology Kharagpur, Kharagpur, West
Bengal, 721302, India, Email: spanda
chem.iitkgp.ac.in
K. K. Das, D. Ghorai, S. Mahato, S. Panda, Synthesis, 2023, 55, 3799-3808.
DOI: 10.1055/a-2147-1336
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Abstract
gem-Diborylalkanes are valuable synthons for diverse C-C bond-forming reactions. A Pd-catalysed hydrogenation of gem-diborylalkenes provides gem-diborylalkanes. gem-Diborylalkenes can be prepared from the corresponding aldehydes and ketones using known procedures.
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Key Words
1,1-diboronates, hydrogenation, hydrogen, palladium/carbon
ID: J66-Y2023
