Transition Metal-Catalyzed Hydro-, Sila-, and Stannastannation of Cyclopropenes: Stereo- and Regioselective Approach toward Multisubstituted Cyclopropyl Synthons
Marina Rubina, Michael Rubin and Vladimir Gevorgyan*
*Department of Chemistry, University of Illinois at Chicago, 845 West Taylor
Street, Chicago, Illinois 60607-7061, Email: vlad
uic.edu
M. Rubina, M. Rubin, V. Gevorgyan, J. Am. Chem. Soc., 2002, 124, 11566-11567.
DOI: 10.1021/ja027095k
see article for more reactions
see article for more examples
Abstract
Highly efficient, stereo- and regioselective palladium-catalyzed hydro-, sila-, and stannastannations of cyclopropenes gave multisubstituted cyclopropylstannanes. The addition across the double bond proceeds from the least hindered face.
see article for more examples
Catalytic Enantioselective Hydrostannation of Cyclopropenes
M. Rubina, M. Rubin, V. Gevorgyan, J. Am. Chem. Soc., 2004, 126, 3688-3689.
Catalytic Enantioselective Hydroboration of Cyclopropenes
M. Rubina, M. Rubin, V. Gevorgyan, J. Am. Chem. Soc., 2003, 125, 7198-7199.
Key Words
ID: J48-Y2002-1290
