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Indium Tribromide Catalyzed Aminolysis of Aziridines: An Efficient Synthesis of vicinal-diamines

J. S. Yadav*, B. V. S. Reddy, K. Vishweshwar Rao, K. Saritha Raj, A. R. Prasad

*Organic Chemistry Division-1, Indian Institute of Chemical Technology, Hyderabad-500 007, India, Email: yadavpubiict.res.in

J. S. Yadav, B. V. S. Reddy, K. Vishweshwar Rao, K. Saritha Raj, A. R. Prasad, Synthesis, 2002, 1061-1064.

DOI: 10.1055/s-2002-31965


Abstract

Indium tribromide catalyzes efficiently the aminolysis of activated aziridines with aromatic amines under mild reaction conditions to afford the corresponding vicinal-diamines in high yields with high selectivity.

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Key Words

aziridines, indium reagents, aryl amines, 1,2-diamines


ID: J66-Y2002-1550