Cross-Couplings of Alkyl Electrophiles under "Ligandless" Conditions: Negishi Reactions of Organozirconium Reagents
Sheryl L. Wiskur, Alexander Korte and Gregory C. Fu*
*Department of Chemistry, Massachusetts Institute of Technology, Cambridge,
Massachusetts 02139, Email: gcf
mit.edu
S. L. Wiskur, A. Korte, G. C. Fu, J. Am. Chem. Soc., 2004, 126, 82-83.
DOI: 10.1021/ja0393729
Abstract
"Ligandless" palladium complexes can catalyze the zirconium-Negishi reactions of alkyl electrophiles. Ligandless processes offer low cost, simplicity, and ease of purification.
see article for more examples
Key Words
ID: J48-Y2004-1350
