Mercury(II)-Catalyzed Regioselective Addition Reaction of Monoesters of Phosphonic Acid to Terminal Alkynes: Synthesis of Vinyl Phosphonates
Aiyun Peng, Yixiang Ding*
*Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China, Email: dingyxmail.sioc.ac.cn
A. Y. Peng, Y. X. Ding, Synthesis, 2003, 205-208.
Various vinyl phosphonates were prepared by the regioselective addition reaction of monoesters of phosphonic acid to alkynes in the presence of Hg(OAc)2/BF3ˇOEt2.
see article for more examples
phosponates, mercury(II)-catalyzed, addition reaction, regioselective, vinyl phosphonate