Cobalt(I)-Catalyzed Stereoselective Olefination of Alkylzinc Reagents with Aldehydes
Jin-Xian Wang*, Ying Fu, Yulai Hu, Kehu Wang
*Institute of Chemistry, Department of Chemistry, Northwest Normal
University, 967 An Ning Road (E.), Lanzhou 730070, P. R. China,
Email: wangjx
nwnu.edu.cn
J.-X. Wang, Y. Fu, Y. Hu, K. Wang, Synthesis, 2003, 1506-1510.
DOI: 10.1055/s-2003-40212
Abstract
The efficient olefination from organozinc reagents with aldehydes is exploited in a new synthesis of aryl and alkyl olefins.
see article for more examples
Rapid and Solvent-Free Synthesis of Homoallyl or Homopropargyl Alcohols Mediated by Zinc Powder
J.-X. Wang, X. Jia, T. Meng, L. Xin, Synthesis, 2005, 2669-2672.
Key Words
zinc, olefination, aldehydes, cobalt, alkenes
ID: J66-Y2003-1890
