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The Enantioselective Tsuji Allylation

Douglas C. Behenna and Brian M. Stoltz*

*Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, Email: stoltzcaltech.edu

D. C. Behenna, B. M. Stoltz, J. Am. Chem. Soc., 2004, 126, 15044-15045.

DOI: 10.1021/ja044812x (free Supporting Information)


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Abstract

Catalytic enantioselective examples of the Tsuji allylation using enol carbonates and enol silanes gave products possessing a quaternary stereogenic center, which are useful building blocks for synthetic chemistry.

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Deracemization of Quaternary Stereocenters by Pd-Catalyzed Enantioconvergent Decarboxylative Allylation of Racemic β-Ketoesters

J. T. Mohr, D. C. Behenna, A. M. Harned, B. M. Stoltz, Angew. Chem. Int. Ed., 2005, 44, 6924-6927.


Key Words

Tsuji-Trost Reaction, Ketones


ID: J48-Y2004-1830