Eco-friendly Oxidative Iodination of Various Arenes with a Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant
Piotr Lulinski, Anna Kryska, Maciej Sosnowski, Lech Skulski*
*Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical
University, 1 Banacha Street, 02-097 Warsaw, Poland, Email: lskulskifarm.amwaw.edu.pl
P. Lulinski, A. Kryska, M. Sosnowski, L. Skulski, Synthesis, 2004, 441-445.
DOI: 10.1055/s-2004-815955
Abstract
Eco-friendly laboratory procedures allow the oxidative iodination of various activated and deactivated arenes with molecular iodine, in the presence of UHP (percarbamide), a stable, strongly H-bonded, solid urea-hydrogen peroxide adduct as the oxidant.
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Key Words
iodoarenes, arenes, halogenation, iodine, peroxides, urea-hydrogen peroxide adduct
ID: J66-Y2004-1960