Copper(II) Tetrafluoroborate-Catalyzed Formation of Aldehyde-1,1-diacetates
Asit K. Chakraborti*, Ramasamy Thilagavathi, Raj Kumar
*National Institute of Pharmaceutical Education and Research (NIPER), Sector 67, S. A. S. Nagar, Punjab - 160062, India, Email: akchakrabortiniper.ac.in
A. K. Chakraborti, R. Thilagavathi, R. Kumar, Synthesis, 2004, 831-833.
DOI: 10.1055/s-2004-816000
Abstract
Aldehyde 1,1-diacetates are efficiently formed in excellent yields from aldehydes and acetic anhydride under solvent-free conditions at room temperature in the presence of a catalytic amount of copper(II) tetrafluoroborate hydrate.
see article for more examples
Copper(II) Tetrafluoroborate-Catalyzed Acetylation of Phenols, Thiols, Alcohols, and Amines
A. K. Chakraborti, R. Gulhane, Shivani, Synthesis, 2004, 111-115.
Key Words
1,1-diacetates, copper compounds, catalysis, solvent-free reactions
ID: J66-Y2004-2030