Synthesis and Fluoride-Promoted Wittig Rearrangements of α-Alkoxysilanes
Robert E. Maleczka, Jr.* and Feng Geng
*Department of Chemistry, Michigan State University, East Lansing, Michigan
48824, Email: maleczka
cem.msu.edu
R. E. Maleczka, Jr., F. Geng, Org. Lett., 1999, 1, 1111-1113.
DOI: 10.1021/ol9909132
Abstract
Upon exposure to CsF, α-alkoxysilanes underwent [2,3]-Wittig rearrangement with an efficiency similar to that realized by the analogous but inherently more toxic α-alkoxystannanes.
see article for more examples
Methyllithium-Promoted Wittig Rearrangements of α-Alkoxysilanes
R. E. Maleczka, Jr., F. Geng, Org. Lett., 1999, 1, 1115-1118.
Key Words
ID: J54-Y1999-510
