Nonmetal-Catalyzed Iodination of Arenes with Iodide and Hydrogen Peroxide
Jernej Iskra*, Stojan Stavber, Marko Zupan
*Laboratory for Organic and Bioorganic Chemistry, Jozef Stefan Institute and
Faculty of Chemistry and Chemical Technology, University of Ljubljana, Jamova
39, 1000 Ljubljana, Slovenia, Email: jernej.iskra
ijs.si
J. Iskra, S. Stavber, M. Zupan, Synthesis, 2004, 1869-1873.
Abstract
A selective and efficient oxidative iodination of electron rich arenes was carried out with one equivalent of KI and two equivalents of 30% hydrogen peroxide in MeOH in the presence of strong acid.
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Key Words
iodination, haloperoxidation, hydrogen peroxide, oxidative halogenation, aromatics
ID: J66-Y2004-2250
