Iridium-catalyzed selective N-allylation of hydrazines
Robert Matunas, Amy J. Lai and Chulbom Lee*
*Department of Chemistry, Princeton University, Princeton, NJ 08544, USA, Email: cblee
princeton.edu
R. Matunas, A. J. Lai, C. Lee, Tetrahedron, 2005, 61, 6298-9308.
DOI: 10.1016/j.tet.2005.03.105
see article for more examples
Abstract
A highly chemo- and regioselective allylic amination of various hydrazones and hydrazides with allylic carbonates proceeds at ambient temperature in the presence of an [Ir(COD)Cl]2/pyridine catalyst, ammonium iodide, and diethylzinc to afford the corresponding N-allylation products in high yields.
see article for more examples
While ads financed 62% of the published abstracts in 2024, donations allowed us to publish additional 12%. 26% of the abstracts have been published voluntarly. If you kindly donate, we can publish more freely accessible information and help the chemical community even more:
If you don't like pawalls or a flood of more and more advertising, then you can send a clear signal here!
Key Words
Iridium, Catalysis, Hydrazones, Hydrazides, Hydrazines, Amination, Allylation
ID: J72-Y2005-2960
