Titanium(IV) Isopropoxide-Catalyzed Formation of 1-Substituted Cyclopropanols in the Reaction of Ethylmagnesium Bromide with Methyl Alkanecarboxylates

Oleg G. Kulinkovich*, Sergei V. Sviridov, Dmitry A. Vasilevski

*Department of Organic Chemistry, Belarussian State University, 4, Skariny av., 220050, Minsk, Belarus, Email: kulinkovichbsu.by

O. G. Kulinkovich, S. V. Sviridov, D. A. Vasilevski, Synthesis, 1991, 234.

DOI: 10.1055/s-1991-26431

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Abstract

1-Substituted cyclopropanols are formed in high yields in the titanium(IV)isopropoxide-catalyzed reaction of esters with ethylmagnesium bromide.

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Key Words

Kulinkovich Reaction, Cyclopropanols

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ID: J66-Y1991-560