Organic Chemistry Portal

Abstracts

Search:

A Convenient Route to 3-Pyrroline Utilizing the Delépine Reaction

Svante Brandänge*, Benito Rodriguez

*Department of Organic Chemistry, Arrhenius Laboratory, University of Stockholm, S-10691 Stockholm, Sweden, Email: svanteorgan.su.se

S. Brandänge, B. Rodriquez, Synthesis, 1988, 347-348.

DOI: 10.1055/s-1988-27571


Abstract

3-Pyrroline has been prepared from (Z)-1,4-dichloro-2-butene in three steps in an overall yield of 74%. The Delépine Reaction permitted the monoamination of the substrate in practically quantitative yields. The subsequent ring-closing reaction was less efficient.



Key Words

Delépine Reaction, Allylamines, 3-Pyrrolines


ID: J66-Y1988-080