Gold(I)-Catalyzed Formation of 5-Methylene-1,3-oxazolidin-2-ones
Andrea Buzas, Fabien Gagosz*
*Laboratoire de Synthèse Organique, UMR CNRS 7652, Ecole Polytechnique, DCSO,
91128 Palaiseau, France, Email:
gagosz
dcso.polytechnique.fr
A. Buzas, F. Gagosz, Synlett, 2006, 2727-2730.
DOI: 10.1055/s-2006-950253
Abstract
A mild and efficient gold(I)-catalyzed rearrangement of propargylic tert-butylcarbamates allows the synthesis of various 5-methylene-1,3-oxazolidin-2-ones, which would be less conveniently obtained using other methods.
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Key Words
gold catalysis, ring closure, oxazolidinones
ID: J60-Y2006-4730
