Iodine as a Chemoselective Reoxidant of TEMPO: Application to the Oxidation of Alcohols to Aldehydes and Ketones
Ross A. Miller* and R. Scott Hoerrner
*Merck Research Laboratories, P.O. Box 2000, Rahway, New Jersey 07065,
Email: ross_miller
merck.com
R. A. Miller, R. S. Hoerrner, Org. Lett., 2003, 5, 285-287.
DOI: 10.1021/ol0272444 (free Supporting Information)
Abstract
Iodine was compared to other positive halogens as terminal oxidant in chemoselective oxidations of alcohols using catalytic TEMPO and was shown to be superior in cases of electron-rich and heteroaromatic benzylic alcohols.
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Key Words
TEMPO, Iodine, Oxidation of Alcohols
Schlüsselworte
TEMPO, Oxidation
ID: J54-Y2003-300
