Highly Selective Oxidative Cleavage of β-Cyclodextrin-Epoxide/Aziridine Complexes with IBX in Water
K. Surendra, N. Srilakshmi Krishnaveni, M. Arjun Reddy, Y. V. D. Nageswar and K. Rama Rao*
*Organic Chemistry Division-I, Indian Institute of Chemical Technology,
Hyderabad-500 007, India, Email: ramaraok
iict.res.in
K. Surendra, N. S. Krishnaveni, M. A. Reddy, Y. V. D. Nageswar, K. R. Rao, J. Org. Chem., 2003, 68, 9119-9121.
DOI: 10.1021/jo034079c
Abstract
IBX has been utilized for the oxidation of various epoxides and aziridines as their β-cyclodextrin complexes in water to afford α-hydroxyketones and α-aminoketones in good yields, respectively.
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K. Surendra, N. Srilakshmi Krishnaveni, M. Arjun Reddy, Y. V. D. Nageswar, K. Rama Rao, J. Org. Chem., 2003, 68, 2058-2059.
Key Words
ring opening, aziridines, epoxides, hydroxyketones, oxidation, IBX, templates, green chemistry
ID: J42-Y2003-900
