Highly Active Catalyst for the Heterogeneous Suzuki-Miyaura Reaction: Assembled Complex of Palladium and Non-Cross-Linked Amphiphilic Polymer
Yoichi M. A. Yamada, Koji Takeda, Hideyo Takahashi and Shiro Ikegami*
*Faculty of Pharmaceutical Sciences, Teikyo University, Sagamiko, Kanagawa
199-0195, Japan, Email: shi-ikepharm.teikyo-u.ac.jp
Y. M. A. Yamada, K. Takeda, H. Takashashi, S. Ikegami, J. Org. Chem., 2003, 68, 7733-7741.
DOI: 10.1021/jo034354v
Abstract
An insoluble, amphiphilic and polymeric palladium catalyst (PdAS) is an excellent catalyst for the Suzuki-Miyaura reaction. The catalyst is reusable after easy work up and showed good stability in any reaction medium.
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Key Words
Suzuki-Miyaura Coupling, Biaryls, Styrenes, Arenes (alkylation), Alkenes, Benzylation
ID: J42-Y2003-990