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Synthesis of arylboronates by the palladium catalysed cross-coupling reaction in ionic liquids

Andrzej Wolan and Marek Zaidlewicz*

*Department of Chemistry, Nicolaus Copernicus University, 87-100 Torun, Poland, Email: zaidlevichem.uni.torun.pl

A. Wolan, M. Zaidlewicz, Org. Biomol. Chem., 2003, 1, 3724-3276.

DOI: 10.1039/b310047b


Abstract

The palladium catalysed cross-coupling reaction of aryl iodides and bromides with pinacolborane in 1,3-dialkylimidazolium tetrafluoroborates and hexafluorophosphates offers simple product isolation by extraction and shorter reaction time as compared to conventional solvents.

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Key Words

Palladium Catalysis, Arylboronates, Ionic Liquids


ID: J52-Y2003-1160