A Silver-Catalyzed Intramolecular Amidation of Saturated C-H Bonds
Yong Cui, Chuan He*
*Department of Chemistry, University of Chicago, 5735 S. Ellis Avenue,
Chicago, IL 60637, USA, Email: chuanhe
uchicago.edu
Y. Cui, C. He, Angew. Chem. Int. Ed., 2004, 43, 4210-4212.
DOI: 10.1002/anie.200454243 (free Supporting Information)
Abstract
An efficient amidation reaction of saturated C-H bonds catalyzed by a unique disilver(I) complex is reported. The reaction is stereospecific and practical for the construction of amine-containing molecules.
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Key Words
amidation, C-H activation, homogeneous catalysis, silver, synthetic methods, protected primary amines, sulfonamides, sultams
ID: J06-Y2004-520
